Degradation of amines during the post-combustion process is unwanted and it is important to understand the mechanisms behind this.
Alkanolamines are well known to absorb acid gasses like CO2. The processes which are based on these types of components are continuously being refined.
Monoethanolamine (MEA) and methyldiethanolamine (MDEA) are absorbents commonly used in CO2 capture.
The CO2 rich flue gas also contains other components like oxygen, SOx, NOx, dust.
These are unwanted components and can result in chemical and thermal degradation of the absorbents.
In the CO2 capture process the absorbents react with the CO2 in the absorption column, and then regenerated in the stripping column by adding heat.
In the regeneration process the waste is retained and collected in a reclaimer.
This waste must be taken care of in an environmentally sound way.